Synthesis and Application of Two Organic Dyes Based on Indoline in Dye-Sensitized Solar Cells

نویسندگان

  • K. Gharanjig Center of Excellence for Color Science and Technology,Department of Organic Colorants, Institute for Color Science and Technology
  • M. Hosseinnezhad Center of Excellence for Color Science and Technology,Department of Organic Colorants, Institute for Color Science and Technology
  • S. Moradian Faculty of Polymer and Color Engineering,Amirkabir University of Technology, Center of Excellence for Color Science and Technology,Institute for Color Science and Technology
چکیده مقاله:

In this paper we sensitized two new organic days dye 1 and dye 2 based on thioindigo with phenothiazine as the electron donor group. We used acrylic acid and cyanoacrylic acid as the electron acceptor anchoring group in dye 1 and dye 2 respectively. The proposed dyes were sensitized from phenothiazine as the starting material by standard reactions and characterized by different techniques such as melting point, FTIR, 1HNMR, elemental analysis and UV-Visible spectroscopy after purification. Spectrophotometric measurements of the syntesised dyes in solution and on a TiO2 substrate were carried out in order to assess changes in the status of the dyes. The wavelength of maximum absorption for dye1 and dye 2 in solution are 499 nm and 505 nm and on TiO2 films are 523 nm and 527 nm, respectively. Finally, the proposed dyes used as sensitizer in a dye solar cell structure and their photovoltaic properties investigated. The Conversion efficiency for dye 1 and dye 2 are 2.34 and 3.07, respectively.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Synthesis and Application of Two Organic Dyes for Dye-Sensitized Solar Cells

In the present study, two new organic dyes based on indigo were prepared and used as sensitizers in dye-sensitized solar cells. To this end, indoxyl was utilized as the electron donor and cyanoacrylic acid as the electron acceptor anchoring groups. These dyes together with their corresponding intermediates were purified and characterized by FTIR, 1HNMR, 13CNMR, elemental analysis and UV-Visible...

متن کامل

Solution-processed organic photovoltaics based on indoline dye molecules developed in dye-sensitized solar cells.

A donor-acceptor (D-A) type indoline dye, D149, was used as an electron donor in solution-processed organic solar cells (OSCs). For bulk-heterojunction (BHJ) type OSCs with PC70BM as electron acceptor, the power conversion efficiency (PCE) is sensitive to the amount of D149 in the D149/PC70BM blend film. When the concentration of D149 in the blend film was as low as 5%, the highest PCE of up to...

متن کامل

Synthesis of Alkyl-functionalized Organic Dyes and Their Application to Dye Sensitized Solar Cells (DSSCs)

Ruthenium dye-based dye-sensitized solar cells (DSSCs) have received great deal of attraction from chemists and material scientists because of their over 10% of photon to current conversion efficiency. The high cost and much synthetic efforts of ruthenium dyes, nevertheless, has often been reported as problematic. Recently, organic dye-based DSSCs whose photon to current conversion efficiency a...

متن کامل

Novel organic dyes for efficient dye-sensitized solar cells.

Two novel metal-free organic dyes containing thienothiophene and thiophene segments have been synthesized. Nano-crystalline TiO2 dye-sensitized solar cells were fabricated using these dyes as light-harvesting sensitizers, and a high solar energy-to-electricity conversion efficiency of 6.23% was achieved.

متن کامل

New Triphenylamine-Based Dyes for Dye-Sensitized Solar Cells

A series of new conjugated metal-free organic dyes (TC1, TC2, TC3, and TC4) comprising triphenylamine (TPA) moieties as the electron donor and cyanoacetic acid moieties as the electron acceptor/anchoring groups were designed at the molecular level and developed for the use in dye-sensitized solar cells (DSCs). Quantum chemical calculations have been performed to gain insight into structural, el...

متن کامل

منابع من

با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ذخیره در منابع من قبلا به منابع من ذحیره شده

{@ msg_add @}


عنوان ژورنال

دوره 8  شماره 4

صفحات  309- 315

تاریخ انتشار 2015-11-01

با دنبال کردن یک ژورنال هنگامی که شماره جدید این ژورنال منتشر می شود به شما از طریق ایمیل اطلاع داده می شود.

میزبانی شده توسط پلتفرم ابری doprax.com

copyright © 2015-2023